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4,5‐Dihydro‐imidazol‐2‐ylidene‐linked palladium complexes as catalysts for the direct CH bond arylation of azoles
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A new outlook in oxidative transformations and coupling reactions via in situ generation of organic chloramines
Owing to their various modes of coordinating and oxidizing reactivity, organic chloramines represent versatile building bl...
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C,O‐Chelated organotin(IV) derivatives as potential anticancer agents: Synthesis, characterization, and cytotoxic activity
Abstract Organotin(IV) chemistry is nowadays in a continuous expansion due to the biological and medicinal potential found...
Applied Organometallic Chemistry
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New nickel (II), cobalt (III), and iron (III) complexes with N′‐[(2‐aminochromon‐3‐yl)methylidene]benzohydrazide: Synthesis, characterization, solvatochromic shift, dipole moment, and DFT calculations
Abstract New Ni (II), Co (III), and Fe (III) complexes of hydrazone (HL) derived from 2-aminochromone-3-carboxaldehyde wit...
Applied Organometallic Chemistry
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Ru(II)–NNO pincer‐type complexes catalysed E‐olefination of alkyl‐substituted quinolines/pyrazines utilizing primary alcohols
Abstract An efficient and selective E-olefination of alkyl-substituted quinolines and pyrazines through acceptorless dehyd...
Applied Organometallic Chemistry
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Synthesis, structure, X‐ray photoelectron spectroscopy (XPS), and antimicrobial, anticancer, and antioxidant activities of Co (III) complexes based on the antihypertensive hydralazine
Abstract The antimicrobial, anticancer, and antioxidant activities of four cobalt (III) complexes, [CoL2]X (X =...
Applied Organometallic Chemistry
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Preclinical assessment of Alzheimer's disease using novel designed 99mTc‐labeled RGD‐based pro‐apoptotic cyclic peptide as a promising SPECT agent
The increased prevalence of neurodegenerative disorders such as Alzheimer's disease, Parkinson's disease, and glioma resul...
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Multinuclear silver N‐heterocyclic carbene complexes provoke potent anticancer activity via mitochondrial dysfunction and cell necrosis induction
Abstract Three silver N-heterocyclic carbene (NHC) complexes (Ag1–Ag3) were designed and synthesized using quinolin...
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Deciphering the mechanism behind efficient enantioselective ethylation with thiazolidine‐based amino alcohols
Taking advantage of the opposite chirality of two privileged starting materials, l-cysteine and d-penicillamine, a wide ra...
Applied Organometallic Chemistry
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A promising strategy for increasing phosphorescent quantum yield: The ligand 10‐cyclic chelate of the tetradentate Pt(II) complex
In this paper, the density functional theory (DFT) and time-dependent density functional theory (TD-DFT) were used to deep...
Applied Organometallic Chemistry
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Rare‐earth metal‐catalyzed hydroboration of unsaturated compounds
Abstract The reduction of unsaturated compounds is one of the most widely applied transformations in organic synthesis. Ag...
Applied Organometallic Chemistry
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Acceleration of FeIII/FeII cycle enhanced by Pd/MOF‐808(Zr) composite in hydrogen promotion Fenton system for sulfamethazine elimination
Abstract Under normal temperature and pressure, a novel improved Fenton system that was named MHACF-MOF-808(Zr) was constr...
Applied Organometallic Chemistry
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Recent advances on the nanocatalyzed synthesis of 1,3‐thiazolidines
1,3-Thiazolidines have attracted a lot of interest due to their biological and pharmaceutical properties. For this reason,...
Applied Organometallic Chemistry
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Exciting progress in the transition metal‐catalyzed synthesis of oxepines, benzoxepines, dibenzoxepines, and other derivatives
Abstract From the past decade so far, the synthesis of seven-membered oxacycles especially natural monocyclic oxepines and...
Applied Organometallic Chemistry
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Synthesis, spectroscopic, theoretical and biological evaluation of novel Schiff base complexes of divalent transition metals
Abstract In the present manuscript, a new series of triazole-based Schiff base, (E)-4-((3-fluoro-4-methoxybenzylidene)amin...
Applied Organometallic Chemistry
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Aerobic epoxidation of olefins by carboxylate ligand‐based cobalt (II) compound: synthesis, X‐ray crystallography, and catalytic exploration
Abstract A new quinoline carboxylate-based cobalt (II) metal compound, [Co (HL1)2(H2O)4] (1) (H2L1 = 2-hydro...
Applied Organometallic Chemistry
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DFT study on the mechanisms of α‐C cross coupling of π‐bonds catalyzed by iron complexes
Abstract The mechanisms of α-C cross coupling of π-bonds catalyzed by iron complexes have been investigated us...
Applied Organometallic Chemistry
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Organometallic (η6‐p‐cymene)ruthenium(II) complexes with thiazolyl‐based organic twigs: En route towards targeted delivery via human serum albumin of the potential anticancer agents
Abstract In this article, we have designed the new ruthenium(II) p-cymene complexes [Ru(η6-p-cymene) HLThz,Me Cl] 1 ...
Applied Organometallic Chemistry
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Synthesis of ferrocene‐based esters by alkylation of carboxylate ions and investigation of their electrochemical and optical behaviors
Abstract The synthesis of new ferrocene-based esters has been studied with the alkylation of a variety of carboxylic acids...
Applied Organometallic Chemistry
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Two tetranuclear Cu2Ln2 (Ln = Dy, Tb) heterometallic complexes: Structure, solution behavior, and magnetic properties
Abstract Two tetranuclear 3d–4f heterometallic complexes [Cu2Ln2(NO3)4(OAc)2L4] (Ln = Dy 1, Tb 2) wer...
Applied Organometallic Chemistry
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Mesoporous MOF composite for efficient removal of uranium, methyl orange, methylene blue, and Congo red dyes from aqueous solutions
Abstract The metal-organic framework (MOF) composites have significant applications in removing water pollutants and heavy...
Applied Organometallic Chemistry
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Synthesis of defected UIO‐66 with boosting the catalytic performance via rapid crystallization
Abstract Due to environmental and health concerns, it is very important to develop high activity oxidative desulfurization...
Applied Organometallic Chemistry
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Nano‐synthesis, solid‐state structural characterization, and antimicrobial and anticancer assessment of new sulfafurazole azo dye‐based metal complexes for further pharmacological applications
Abstract A new azo dye ligand (abbreviated as H3L) derived from coupling of sulfafurazole diazonium salt with 2,4-dihydrox...
Applied Organometallic Chemistry
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Influence of co‐ligand on the biological properties of Schiff base metal complexes: Synthesis, characterization, cytotoxicity, and antimicrobial studies
In this work, six new mixed ligand Schiff base metal complexes of [M2(L1)(X)2Cl4] type, (where, M = CoII, Ni...
Applied Organometallic Chemistry
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Synthesis, spectroscopic and thermal studies of Cu+2, Ni+2 and Co+3 complexes of Schiff base containing furan moiety. Antitumor, antioxidant, antibacterial and DNA interaction studies
Three mononuclear bioefficient imine-based coordination complexes [Cu(FMIMBCP)2] (1), [Ni(FMIMBCP)2] (2), and [Co(FMIMBCP)...
Applied Organometallic Chemistry
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A strategy of designed anionic metal–organic framework adsorbent based on reticular chemistry for rapid selective capture of carcinogenic dyes
Abstract In this work, highly effective and rapid removal of cationic carcinogenic organic dye molecules is achieved throu...
Applied Organometallic Chemistry
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Novel metal complexes with pyrano[3,2‐c]quinoline‐3‐carboxaldehyde: Synthesis, spectroscopic, molecular modeling, QSAR, antimicrobial, and antitumor studies
Reaction of 6-ethyl-4-hydroxy-2,5-dioxo-5,6-dihydro-2H-pyrano[3,2-c]quinoline-3-carboxaldehyde (HL) with some metal ions, ...
Applied Organometallic Chemistry
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Half‐sandwich ruthenium complex with a very low overpotential and excellent activity for water oxidation under acidic conditions
Abstract Molecular catalysts are acknowledged for the ability to design reaction sites within well-defined structures to a...
Applied Organometallic Chemistry
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Some characteristics of new and innovative COX inhibitor derivatives: Potent hCA‐I and hCA‐II inhibitors supported by molecular docking studies
Abstract In this study, two novel metallophthalocyanines (ZnPc and CoPc) were synthesized using the corresponding metal sa...
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Synthesis, characterization, and some metal complexes of bis(isocyanide)disiloxane, showing catalytic activity
Abstract Isocyanides (isonitriles) are unique organic compounds that contain a formally divalent carbon. Herein, the synth...
Applied Organometallic Chemistry
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