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The salt effect: kinetics and thermodynamics
The salt effect: kinetics and thermodynamics
The primary kinetic salt effect is reviewed and a generalized Brönsted–Bjerrum equation is presented. The class...
Introduction to electrochemical science using Legendre transforms
Introduction to electrochemical science using Legendre transforms
The Legendre transform is a mathematical method that is very useful for finding basic equations that describe electrical s...
(+)-Nootkatone, the flavor of grapefruit
(+)-Nootkatone, the flavor of grapefruit
Nootkatone is one of the most valuable citrus flavors. Originally isolated from the heartwood of the Nootka cypress (Calli...
Tyrosinases: a family of copper-containing metalloenzymes
Tyrosinases: a family of copper-containing metalloenzymes
Tyrosinases (TYRs) are a family of copper-containing metalloenzymes that are present in all domains of life. TYRs catalyze...
The ideal gas law: derivations and intellectual background
The ideal gas law: derivations and intellectual background
A detailed overview of the origins and possible derivations of the ideal gas law are given in this lecture text. The tacit...
Periodic arrangements of closely packed spheres
Periodic arrangements of closely packed spheres
The symmetry aspects of close packing of hexagonal layers of equal spheres are usually presented with reference to the two...
Systematic toxicological analysis in forensic and clinical laboratories: a challenging task of analytical chemistry
Systematic toxicological analysis in forensic and clinical laboratories: a challenging task of analytical chemistry
This lecture text presents the chemical analysis used for the investigation of a suspected poisoning in clinical and foren...
Arylation of C=C bonds via non-cross-coupling reactions: historical evolution of the Meerwein arylation mechanisms
Arylation of C=C bonds via non-cross-coupling reactions: historical evolution of the Meerwein arylation mechanisms
The arylation of olefines had a milestone year in 1939 when Hans Meerwein (1879–1965) reported that olefins could re...
The chemistry behind paper restoration: diagnostic techniques and cutting-edge innovation
The chemistry behind paper restoration: diagnostic techniques and cutting-edge innovation
The conservation of ancient paper and manuscripts is a complex and evolving field that combines historical understanding, ...
Effect of Nanoparticle Size on the Stability and Efficiency of Silver Nanofluids in Solar Thermal Systems
Effect of Nanoparticle Size on the Stability and Efficiency of Silver Nanofluids in Solar Thermal Systems
Silver nanofluids have emerged as promising candidates for advanced thermal and optical applications due to their excellen...
Solvate Complexes of Lithium Salts with Sulfolane as Electrolytes for Advanced Energy Storage Devices
Solvate Complexes of Lithium Salts with Sulfolane as Electrolytes for Advanced Energy Storage Devices
The composition of solvate complexes of LiClO4, LiSO3CF3, LiN(SO2CF3)2, LiBF4, and LiPF6 with sulfolane formed from lithiu...
Sulfonated Biochar Derived from Eucalyptus Bark as Natural Catalyst in the Biginelli Reaction
Sulfonated Biochar Derived from Eucalyptus Bark as Natural Catalyst in the Biginelli Reaction
The Biginelli products (dihydropyrimidines) and their derivatives are among the most abundant types of organic compounds. ...
New 4-Thiazolidinone-Bearing Fluoroquinolone Derivatives: Synthesis, Antimicrobial Effectiveness, Structural Characterization, and In Silico Docking Analysis
New 4-Thiazolidinone-Bearing Fluoroquinolone Derivatives: Synthesis, Antimicrobial Effectiveness, Structural Characterization, and In Silico Docking Analysis
A series of ciprofloxacin-based thiazolidinone derivatives were developed and prepared by reacting active methylene compou...
Molecular Docking and Spectroscopic Exploring of the Binding Intermolecular between BSA with Complex of Zirconium
Molecular Docking and Spectroscopic Exploring of the Binding Intermolecular between BSA with Complex of Zirconium
In this study, the mechanism of the binding interaction of Zr(CUR), a novel six-coordinate complex of zirconium with a cur...
Design, Synthesis, and Activity Evaluation of Endogenous Hydrogen Sulfide Inhibitor of MRSA
Design, Synthesis, and Activity Evaluation of Endogenous Hydrogen Sulfide Inhibitor of MRSA
Eighteen indole target compounds were synthesized from 3-(6-bromo-3-indolyl)propionic acid. The chemical structures were d...
Interaction of Baclofen with Vanillin in Aqueous Acidic Medium: Kinetics, Mechanism and Computational Studies
Interaction of Baclofen with Vanillin in Aqueous Acidic Medium: Kinetics, Mechanism and Computational Studies
The reaction of vanillin (Van) with baclofen (Bac) was studied kinetically in an aqueous acidic medium. The reaction produ...
Ultrasound-Promoted Ferrite Catalyzed One-Pot Multicomponent Synthesis of 3,4-Disubstituted Isoxazole-5(4)-one Derivatives in Water as a Green Solvent with Evaluation of Antimicrobial Activity
Ultrasound-Promoted Ferrite Catalyzed One-Pot Multicomponent Synthesis of 3,4-Disubstituted Isoxazole-5(4)-one Derivatives in Water as a Green Solvent with Evaluation of Antimicrobial Activity
A systematic and efficient green method for the synthesis of advanced derivatives of isoxazole at room temperature was dev...
Targeted Breast Cancer Combat: The Pioneering Role of Hesperidin-Infused pH and Thermosensitive Nanoparticles
Targeted Breast Cancer Combat: The Pioneering Role of Hesperidin-Infused pH and Thermosensitive Nanoparticles
This study aimed to improve the bioavailability and increase the therapeutic efficacy of Hes against breast cancer by usin...
Design, Efficient One-Step Synthesis of Bromo--hydroxybenzamides and Herbicidal Activity Evaluation
Design, Efficient One-Step Synthesis of Bromo--hydroxybenzamides and Herbicidal Activity Evaluation
Discovering super-efficient herbicides with novel structures is one of the effective ways to solve the increasingly severe...
Fabrication of a BiVO/CuCoO Heterojunction Photoanode for Photoelectrochemical Water Splitting
Fabrication of a BiVO/CuCoO Heterojunction Photoanode for Photoelectrochemical Water Splitting
Bismuth vanadate (BiVO4) is highly studied for its potential in photoelectrochemical (PEC) water splitting, but its effect...
Synthesis and Properties of Phthalonitriles with 2-Phenylphenoxy Groups and Corresponding Metallophthalocyanines
Synthesis and Properties of Phthalonitriles with 2-Phenylphenoxy Groups and Corresponding Metallophthalocyanines
4-(2-Phenylphenoxy)-5-nitro- and 4,5-di(2-phenylphenoxy)phthalonitriles were obtained by the reaction of 4-bromo-5-nitroph...
Microwave-Assisted Green Synthesis, In Silico Study, and Plant Growth Stimulant Activity of Novel 3-(2-Arylidenehydrazinyl)-6-chloropyridazines
Microwave-Assisted Green Synthesis, In Silico Study, and Plant Growth Stimulant Activity of Novel 3-(2-Arylidenehydrazinyl)-6-chloropyridazines
Based on 3-chloro-6-hydrazinylpyridazine, a series of new derivatives containing the arylidenehydrazinyl-6-chloropyridazin...
Preparation of Chestnut Shell Biochar Loaded with Zinc/Manganese for Effective Removal of Oxytetracycline from Aqueous Solution
Preparation of Chestnut Shell Biochar Loaded with Zinc/Manganese for Effective Removal of Oxytetracycline from Aqueous Solution
Abandoned biomass derived from agricultural production has been widely applied to deal with environmental challenges. This...
Thiourea-Catalyzed Glycosylation: A Breakthrough in Stereoselective Synthesis of Oligosaccharides
Oligosaccharides are vital biomolecules that play an essential role in various biological functions. For studying biochemi...
A [CuII24] truncated octahedron and its [CuII8] building block
Reaction of CuCl2·2H2O with p-tert-butylthiacalix[4]arene (H4TC[4]A) affords a [CuII24] cage whose metallic skeleton ...
DBU-promoted cascade phosphorylation/cyclization for the synthesis of phosphorylated 3-aminoindoles
DBU-promoted cascade phosphorylation/cyclization for the synthesis of phosphorylated 3-aminoindoles A novel strategy of ca...
Recent development of azahelicenes showing circularly polarized luminescence
Recently, a variety of circularly polarized luminescence (CPL) dyes have been developed as next-generation chiroptical mat...
NiCo Alloy Particles Decorated on TiO2 Nanoarray as an Efficient Electrocatalyst for Nitrite Reduction to Ammonia
Electrocatalytic nitrite (NO2−) reduction (NO2−RR) is a potential environmentally friendly method for producing NH3 effici...
Direct and chemoselective transformation of cysteine to dehydroalanine on peptides
A direct method for the preparation of peptides containing a dehydroalanine residue was developed through the chemoselecti...
Novel Perovskite-Based Betavoltaic Cell: Dual Additive Strategy for Enhanced FAPbI3 α-phase Stability and Performance
By utilizing chlorine-based dual additives with perovskite film and radioactive isotopes of carbon nanoparticles/quantum d...
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