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Photoactivable Ru(II) Polypyridyl Complexes as Dual Action Modulators of Amyloid-Beta Peptide Aggregation and Cu Redox Cycling
The misfolding and aggregation of the amyloid-β (Aβ) peptide is a major hallmark of Alzheimer's disease (AD), yet ther...
Elucidating the reaction kernel and probing the effect of anharmonicity in the ring-closing reaction of fulgide single crystals
Chemistry involves dynamics that transform chemical structures from one form to another. However, among the vast milieu of...
High-Throughput Electronic Property Prediction of Cyclic Molecules with 3D-Enhanced Machine Learning
Complex organic molecules play a pivotal role in bioactive compounds and organic functional materials, yet existing molecu...
Constructing Photoferroelectric Semiconductor by Regulating Non-Covalent Interactions through Halogen Substitution
The advantages of molecular ferroelectrics lie in the 'designability' and 'multifunctionality', and the mo...
A Photochemical Strategy for Aromatic Nitrogen ortho- Isomerization
Anilines are essential functional groups in bioactive molecules. Their aromatic substitution pattern governs key physicoch...
Supramolecular covalency of halogen bond revealed by NMR contact shift in paramagnetic cocrystals
Despite the supramolecular interactions such as halogen bonding are frequently termed 'noncovalent' interactions, ...
Ligand-mediated asymmetric dicopper sites for robust catecholase-mimicking catalysis and selective sensing
Fabricating dicopper centers in nanozymes offered a promising route to mimic catecholase-like catalysis. However, some dic...
Unveilling photoinduced electron transfers in photosensitized polyoxometalates for solar energy conversion.
Artificial photosynthesis faces the challenge of developing visible-light-driven strategies for converting and storing sol...
Stabilizing the oxygen anionic redox chemistry by Li-deficient and Li-rich biphasic structure for high-energy Li-ion batteries
Li-rich layered oxides (LLOs) with a large specific capacity of ~300 mAh g -1 show promise for developing high-energy Li-i...
Monitoring Structural Change and Drug Release of Responsive Nanoparticles Using Polarity-Sensitive Fluorophores.
Stimuli-responsive polymeric nanoparticles have the potential to radically enhance the delivery of therapeutic cargo inclu...
Hydroxyl Radical Generation from H2O2 via Liquid-Liquid Contact-Electro-Catalysis
Contact-electro-catalysis (CEC) has emerged as a promising strategy for reactive oxygen species (ROS) generation, primaril...
Macrocycle Formation-Mediated Augmentation in Reactive Oxygen Species Production
While the synthesis of methylene-bridged fluorescent macrocycles has attracted significant research interest, their abilit...
Observation of shuttling on the one-second timescale in a [10]cycloparaphenylene/C60 [2]catenane
[2]Catenanes comprising two identical binding sites are an excellent platform to study the kinetics of non-covalent intera...
Isomeric decker metallo-supramolecules with tunable luminescence and chiroptical properties
The regulation of interchromophoric interactions in multichromophoric systems is crucial for developing high-performance p...
Accessing Homoleptic Neutral and Anionic Five-coordinate Pr(IV) Siloxide Complexes
Structurally characterized Pr(IV) complexes are limited to four examples because the ligands and reaction conditions capab...
Preparation, single crystal structure and room-temperature phosphorescence of a covalent organic polymer containing Te-O-P bonds
Room-temperature phosphorescent (RTP) single crystals of covalent organic polymers (COPs) are rarely reported due to the h...
Multiple Effects of Aromatic Substituents on Excited State Properties and Singlet Fission Process in Azaquinodimethane System
Singlet fission (SF) could offset thermalization loss of high-energy photons via multiexciton generations, thus holding gr...
Status and Outlook of Solid Electrolyte Membrane Reactors for Energy, Chemical, and Environmental Applications
Solid electrolyte membrane-based reactors (SEMRs) can be operated at super high temperatures with distinct reaction kineti...
In Situ Raman Spectroscopic Studies of CO2 Reduction Reactions: From Catalyst Surface Structures to Reaction Mechanisms
A bstractThe electrochemical CO2 reduction reaction (eCO2RR) has gained widespread attention as an important techn...
Helix-Induced Full-color Circularly Polarized Luminescence Films with Multiple Information Encryption and Multi-stimuli Responsiveness
The development of full-color circularly polarized luminescence (CPL) materials is of great significance in the field of l...
Heterogeneously Catalyzed Supramolecular Polymerization: Essential Roles of Nucleation and Fragmentation-Induced Autocatalysis in Chiral Transfer
The complexity of multi-component molecular assembly demands precise control strategies to enhance both efficiency and sel...
Operando evidence on the chirality-enhanced oxygen evolution reaction in intrinsically chiral electrocatalysts†
Electrolytic hydrogen is identified as a crucial component in the desired decarbonisation of the chem- ical industry, util...
A Photo- and Cobalt-Catalyzed Highly Selective and Divergent Hydrofunctionalization of 1,3-Dienes with Phenols
An applicable cobalt-hydride mediated selective, divergent hydroetherification and sequential hydroetherification/hydroary...
Photocatalytic 1,3-Difluoroalkylcarboxylation of Alkenes by Triple Kinetic-Controlled Radical Self-Ordering
A transition metal-free protocol for the unsymmetrical radical 1,3-difunctionalization of alkenes has been established for...
A Switch-On Luminescent Europium(III) Probe for Selective and Time-Resolved Detection of Adenosine Diphosphate (ADP)
Adenosine diphosphate (ADP) is a key product of two essential classes of biological reactions, catalysed by ATPases and ki...
Water-stable metal-organic frameworks (MOFs): rational construction and carbon dioxide capture
Metal-organic frameworks (MOFs) are considered to be a promising porous material due to their excellent porosity and chemi...
Machine learning from quantum chemistry to predict experimental solvent effects on reaction rates
Fast and accurate prediction of solvent effects on reaction rates are crucial for kinetic modeling, chemical process desig...
Breaking the trade-off between capacity and stability in vanadium-based zinc-ion batteries
Water in electrolytes is a double-edged sword in zinc-ion batteries (ZIBs). While it allows for proton insertion in the ca...
Probing the Functional Hotspots Inside Protein Hydrophobic Pockets by In-Situ Photochemical Trifluoromethylation and Mass Spectrometry
Due to the complex high-order structures and interactions of proteins within aqueous solution, majority of chemical functi...
Artificial Design of Organic Emitters via a Genetic Algorithm Enhanced by a Deep Neural Network
The design of molecules requires multi-objective optimizations in high-dimensional chemical space with often conflicting t...
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